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ChemInform Abstract: Rh(I)-Catalyzed Carbonylative Ring Opening of Diazabicycles with Acyl Anion Equivalents.

✍ Scribed by Frederic Menard; Christian Frederik Weise; Mark Lautens


Publisher
John Wiley and Sons
Year
2008
Weight
29 KB
Volume
39
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Lanthanoid-Catalyze
✍ Y. TANIGUCHI; S. TANAKA; T. KITAMURA; Y. FUJIWARA πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 33 KB πŸ‘ 1 views

Lanthanoid-Catalyzed Ring-Opening Reaction of Epoxides with Acyl Halides. -Eu(dpm) 3 is found to be the best reagent for ring-opening reaction of epoxides with acyl halides. In the case of cyclohexene oxide (I), a trans addition produces (III) stereoselectively. Propylene oxide affords a mixture of