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ChemInform Abstract: Lanthanoid-Catalyzed Ring-Opening Reaction of Epoxides with Acyl Halides.

✍ Scribed by Y. TANIGUCHI; S. TANAKA; T. KITAMURA; Y. FUJIWARA

Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

Lanthanoid-Catalyzed Ring-Opening Reaction of Epoxides with Acyl Halides.

-Eu(dpm) 3 is found to be the best reagent for ring-opening reaction of epoxides with acyl halides. In the case of cyclohexene oxide (I), a trans addition produces (III) stereoselectively. Propylene oxide affords a mixture of the regioisomers; epichlorohydrin affords a single product. -(TANIGUCHI,

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