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ChemInform Abstract: Ring Opening Reaction of Epoxides with Diphenyl Phosphorazidate.

✍ Scribed by Masanori Mizuno; Takayuki Shioiri

Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis

1999 cleavage reactions, decomposition reactions, pyrolysis cleavage reactions, decomposition reactions, pyrolysis O 0100 48 -056 Ring Opening Reaction of Epoxides with Diphenyl Phosphorazidate. -Epoxides (I) and (IV) undergo regio-and stereoselective reaction with diphenyl phosphorazidate (II) in the presence of DMAP and LiClO 4 . Vicinal azidohydrins such as (III) and (V) are obtained as products. For Ξ±,Ξ²-unsaturated carbonyl compounds [cf. (VI)] only the corresponding Ξ±-azidovinyl derivatives (VII) are isolated.

-(MIZUNO, MASANORI; SHIOIRI, TAKAYUKI;

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