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S,O-Acetals as Novel “Chiral Aldehyde” Equivalents.

✍ Scribed by Barry M. Trost; Matthew L. Crawley; Chul Bom Lee

Book ID
101986103
Publisher
John Wiley and Sons
Year
2006
Weight
36 KB
Volume
37
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

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A “Chiral Aldehyde” Equivalent as a Buil
A “Chiral Aldehyde” Equivalent as a Building Block Towards Biologically Active Targets
✍ Barry M. Trost; Matthew L. Crawley 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 446 KB

## Abstract Chiral γ‐aryloxybutenolides, readily accessible through dynamic kinetic asymmetric transformation (DYKAT) of racemic acyloxybutenolides, were utilized as “chiral aldehyde” building blocks for intermolecular cycloadditions and Michael reactions. Unprecedented selectivity in trimethylenem