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ChemInform Abstract: Zinc-Induced Novel Reductive Cyclodimerization of Some α,β-Unsaturated Ketones.

✍ Scribed by Sankar P. Dey; Asok K. Mallik


Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
30
Category
Article
ISSN
0931-7597

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Low-Valent Titanium Induced Novel Reductive Cyclizations of α,β-Unsaturated Nitrile Compounds. -Cyclopentenes such as (II), (IV), and (VII) are easily prepared by cyclodimerization of α,β-unsaturated nitriles promoted by low-valent titanium reagent. Using the same reagent for nitro-compounds such a