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ChemInform Abstract: A Novel Cyclodimerization of α,β-Unsaturated Ketones Induced by Low-Valent Titanium.

✍ Scribed by L. ZHOU; D. SHI; Y. GAO; W. SHEN; G. DAI; W. CHEN

Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
28
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Low-Valent Titanium
ChemInform Abstract: Low-Valent Titanium Induced Novel Reductive Cyclizations of α,β-Unsaturated Nitrile Compounds.
✍ L. ZHOU; S. TU; D. SHI; G. DAI; W. CHEN 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 38 KB

Low-Valent Titanium Induced Novel Reductive Cyclizations of α,β-Unsaturated Nitrile Compounds. -Cyclopentenes such as (II), (IV), and (VII) are easily prepared by cyclodimerization of α,β-unsaturated nitriles promoted by low-valent titanium reagent. Using the same reagent for nitro-compounds such a