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ChemInform Abstract: Tripod Ligands Containing a Mixed P/N/S Donor Set: Synthesis and Coordination Chemistry.

โœ Scribed by A. JACOBI; G. HUTTNER; U. WINTERHALTER


Publisher
John Wiley and Sons
Year
2010
Weight
27 KB
Volume
28
Category
Article
ISSN
0931-7597

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โœฆ Synopsis


Tripod Ligands Containing a Mixed P/N/S Donor Set: Synthesis and Coordination Chemistry.

-Neopentane-based tripod ligands such as (I) and (II) are prepared in a convergent manner and their coordination capabilities are investigated in a series of molybdenum carbonyl complexes.


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Pyrazole as a Donor Function in Neopenta
โœ Albrecht Jacobi; Gottfried Huttner; Ute Winterhalter; Sven Cunskis ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 708 KB

The chlorine functions of CH 3 C(CH 2 Cl) 3 , 1, may be replaced involved in intramolecular hydrogen bonding to the CH 2 OH function (Nโ€ขโ€ขโ€ขH-O distance 280 pm). Blocking of the OH by pyrazolyl (pz) as well as imidazolyl (im) residues under the conditions of nucleophilic substitution leading to tripod