Functionalized tripod ligands / Mixed donor set ligands / Solubilized tripod ligands / Molybdenum / Iron / Neopentane-derived tripod ligands of the general type electrophiles will produce the corresponding ether derivatives ROCH 2 C(CH 2 PPh 2 )(CH 2 Z) 2 (3). Mesylation of 2 HOCH 2 C(CH 2 PPh 2 )(C
ChemInform Abstract: Functionalized Ether Derivatives of HOCH2C(CH2PPh2)3 and Related Tripod Ligands — Synthesis and Coordination Chemistry.
✍ Scribed by P. SCHOBER; R. SOLTEK; G. HUTTNER; L. ZSOLNAI; K. HEINZE
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 38 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0931-7597
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Tripod ligands RCH 2 C(CH 2 PPh 2 )(CH 2 X)(CH 2 Y) (1) with X, strongly coordinate in compounds such as [η 3 -{CH 3 C(CH 2 PPh 2 ) 2 (CH 2 S)}(CO) 3 Mo] -which are obtained as Y = SAlkyl, SBzl selectively undergo reductive cleavage of the SBzl function with Li/NH 3 /THF at -40 °C to produce their l
The chlorine functions of CH 3 C(CH 2 Cl) 3 , 1, may be replaced involved in intramolecular hydrogen bonding to the CH 2 OH function (N•••H-O distance 280 pm). Blocking of the OH by pyrazolyl (pz) as well as imidazolyl (im) residues under the conditions of nucleophilic substitution leading to tripod
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