Tripod ligands RCH 2 C(CH 2 PPh 2 )(CH 2 X)(CH 2 Y) (1) with X, strongly coordinate in compounds such as [η 3 -{CH 3 C(CH 2 PPh 2 ) 2 (CH 2 S)}(CO) 3 Mo] -which are obtained as Y = SAlkyl, SBzl selectively undergo reductive cleavage of the SBzl function with Li/NH 3 /THF at -40 °C to produce their l
ChemInform Abstract: Thiolate and Thioether Functions as Donor Groups X, Y in Tripod Ligands RCH2C(CH2PPh2)(CH2X) (CH2Y) — Synthesis and Coordination Chemistry.
✍ Scribed by R. SOLTEK; G. HUTTNER
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 36 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0931-7597
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