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ChemInform Abstract: Total Synthesis of Theopederin D.

✍ Scribed by Michael E. Green; Jason C. Rech; Paul E. Floreancig

Publisher
John Wiley and Sons
Year
2008
Weight
19 KB
Volume
39
Category
Article
ISSN
0931-7597

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Total Synthesis of Theopederin D
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✍ Michaelβ€…E. Green; Jasonβ€…C. Rech; Paulβ€…E. Floreancig πŸ“‚ Article πŸ“… 2008 πŸ› John Wiley and Sons 🌐 English βš– 334 KB πŸ‘ 1 views
Total Synthesis of Theopederin D
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✍ Michaelβ€…E. Green; Jasonβ€…C. Rech; Paulβ€…E. Floreancig πŸ“‚ Article πŸ“… 2008 πŸ› John Wiley and Sons 🌐 English βš– 334 KB πŸ‘ 2 views
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A Synthesis of Theopederin D and a Formal Synthesis of Pederin. -The first synthesis of theopederin D (IV), a cytotoxic metabolite from a marine sponge, based on the coupling of two advanced intermediates (I) and (II) is described. Moreover, an improved synthesis of the amide (VIII), a key intermed

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An Enantioselective Total Synthesis of (+)-Methyl Pederate. -The key intermediate for theopederins, methyl pederate (IV), is available by a practical route involving the pivotal Pd-catalyzed cyclization of the carbonate (II) as key step. -(TOYOTA, M.;