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ChemInform Abstract: Total Synthesis of Spirotryprostatin B via Asymmetric Nitroolefination.

✍ Scribed by Trusar D. Bagul; Gingipalli Lakshmaiah; Takeo Kawabata; Kaoru Fuji

Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
33
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable via the β€œReferences” option.

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The Total Synthesis of Spirotryprostatin A. -Key step in the synthesis of the title alkaloid (XI) which is found in the fermentation broth of Aspergillus fumigatus and which manifests cell cycle inhibition at the G2/M phase, is the rearrangement of a bromohydrin prepared in situ from Ξ²-carboline de