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ChemInform Abstract: The Asymmetric Total Synthesis of (+)- and (-)-Spirotryprostatin B.

✍ Scribed by Paul R. Sebahar; Robert M. Williams

Publisher
John Wiley and Sons
Year
2000
Weight
30 KB
Volume
31
Category
Article
ISSN
0931-7597

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The Total Synthesis of Spirotryprostatin A. -Key step in the synthesis of the title alkaloid (XI) which is found in the fermentation broth of Aspergillus fumigatus and which manifests cell cycle inhibition at the G2/M phase, is the rearrangement of a bromohydrin prepared in situ from Ξ²-carboline de