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ChemInform Abstract: Total Synthesis of Papuamine via a Stereospecific Intramolecular Imino Ene Reaction of an Allenylsilane.

โœ Scribed by R. M. BORZILLERI; S. M. WEINREB; M. PARVEZ


Book ID
112021407
Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
26
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Application of a St
โœ J. JIN; S. M. WEINREB ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 29 KB ๐Ÿ‘ 2 views

## Application of a Stereospecific Intramolecular Allenylsilane Imino Ene Reaction to Enantioselective Total Synthesis of the 5,11-Methanomorphanthridine Class of Amaryllidaceae Alkaloids. -Starting from the enantiomerically pure epoxy alcohol (I) the allenylsilane aldehyde (II) is prepared. Its