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ChemInform Abstract: A Convergent Enantioselective Total Synthesis of (-)-Perhydrohistrionicotoxin with an Intramolecular Imino Ene-Type Reaction as a Key Step.

✍ Scribed by D. TANNER; L. HAGBERG


Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
29
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Application of a St
✍ J. JIN; S. M. WEINREB πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 29 KB πŸ‘ 1 views

## Application of a Stereospecific Intramolecular Allenylsilane Imino Ene Reaction to Enantioselective Total Synthesis of the 5,11-Methanomorphanthridine Class of Amaryllidaceae Alkaloids. -Starting from the enantiomerically pure epoxy alcohol (I) the allenylsilane aldehyde (II) is prepared. Its