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Total Synthesis of Papuamine via a Stereospecific Intramolecular Imino Ene Reaction of an Allenylsilane

โœ Scribed by Borzilleri, Robert M.; Weinreb, Steven M.; Parvez, Masood

Book ID
121263739
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
221 KB
Volume
116
Category
Article
ISSN
0002-7863

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โœ J. JIN; S. M. WEINREB ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 29 KB ๐Ÿ‘ 2 views

## Application of a Stereospecific Intramolecular Allenylsilane Imino Ene Reaction to Enantioselective Total Synthesis of the 5,11-Methanomorphanthridine Class of Amaryllidaceae Alkaloids. -Starting from the enantiomerically pure epoxy alcohol (I) the allenylsilane aldehyde (II) is prepared. Its