ChemInform Abstract: Total Synthesis of Apoptolidin A.
β Scribed by Michael T. Crimmins; Hamish S. Christie; Alan Long; Kleem Chaudhary
- Publisher
- John Wiley and Sons
- Year
- 2009
- Weight
- 15 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Abstract
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π SIMILAR VOLUMES
## Abstract The total synthesis of apoptolidin A is described employing an early glycosylation strategy. Strategic disconnections were chosen between C11βC12 (crossβcoupling) and C19OβC1 (macrocyclization). The __cis__βselective glycosylation at C9βOH was achieved with the new SIBA protective group