ChemInform Abstract: Total Synthesis and Proof of Relative Stereochemistry of (-)-Aureonitol.
β Scribed by Peter J. Jervis; Liam R. Cox
- Publisher
- John Wiley and Sons
- Year
- 2009
- Weight
- 26 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0931-7597
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Determination of Relative and Absolute Stereochemistry of Cephalosporolide D and Its Enantioselective Total Synthesis. -The title compound (XI) is synthesized in an efficient approach via an aldol reaction of (II) and (III) as key step. (R)-(I) is obtained from commercially available methyl (R)-3-h