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ChemInform Abstract: Theoretical Confirmation of the Stereoselectivity in the Reverse Brook Rearrangement.

✍ Scribed by Yigui Wang; Michael Dolg

Publisher
John Wiley and Sons
Year
2010
Weight
24 KB
Volume
31
Category
Article
ISSN
0931-7597

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Confirmation of Theoretical Predictions. -A systematic study of competitive reactions of the title compounds (I) and (II), generated by flash pyrolysis of (III) and (IX), with a variety of polar reagents is described. The reactivities towards (I) follows the general order amines ΒΏ alcohols β‰₯ aldehyd