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ChemInform Abstract: The Synthesis of the Monomeric Moiety of Disorazole C1.

โœ Scribed by M. C. Hillier; D. H. Park; A. T. Price; R. Ng; A. I. Meyers


Publisher
John Wiley and Sons
Year
2010
Weight
35 KB
Volume
31
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Synthesis of the Mo
โœ M. A. BRIMBLE; L. J. DUNCALF; S. J. PHYTHIAN ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 34 KB ๐Ÿ‘ 1 views

Synthesis of the Monomeric Unit of ฮณ-Actinorhodin. -The title unit (XII) is synthesized for the first time via the addition of (VII) to (VI) followed by oxidative rearrangement of the obtained (VIII) to (IX) as the two key steps. Deprotection of dimethyl ether (XI) proceeds with epimerization at C-