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ChemInform Abstract: Enantioselective Synthesis of a C1—C9 Moiety of Tylonolide, Tylosin Aglycon.

✍ Scribed by I. BERQUE; P. LE MENEZ; P. RAZON; A. PANCRAZI; J. ARDISSON; J.-D. BRION

Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
30
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Allyltitanates in Stereospecific Additions to Chiral δ-Lactol: Efficient Enantioselective Route to a Potential Precursor of the C1—C9 Portion of Tylonolide.
✍ Isabelle Berque; Patrick Le Menez; Patrick Razon; Jacqueline Mahuteau; Jean-Pier 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 38 KB 👁 1 views

Allyltitanates in Stereospecific Additions to Chiral δ-Lactol: Efficient Enantioselective Route to a Potential Precursor of the C 1 -C 9 Portion of Tylonolide. -The allyltitanate generated from the carbamate (I) is found to react with the aldehyde (II) to afford the anti adduct (III) with high dias