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ChemInform Abstract: Toward a Total Synthesis of an Aglycone of Spiramycine; Two Complementary Accesses to a C-5/C-9 Fragment.

✍ Scribed by G. ODDON; D. UGUEN

Publisher
John Wiley and Sons
Year
2010
Weight
27 KB
Volume
28
Category
Article
ISSN
0931-7597

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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable v

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Toward a Total Synthesis of Pristinamycin II B ; a Chiron Approach to a C-9/C-16 Fragment. -Starting from readily available (S)-malic acid derivative (I), an appreciable amount (ca. 2 g) of the title fragment (XV) is prepared using the Grignard reaction of the propargyl diol (VI) as the key step. T