Enantioselective Intramolecular C-H Insertion Route to a Key Intermediate for the Synthesis of Trinem Antibiotics. -The new route to the chiral azetidin-2-one title compound (III) is based on the Rh-catalyzed decomposition of the diazoester (I) and following intramolecular carbene C-H insertion. Th
✦ LIBER ✦
ChemInform Abstract: The Synthesis of a Key Intermediate (I) en Route to Gelsemine: A Program Based on Intramolecular Displacement of the Carbon—Oxygen Bond of a Strategic Oxetane.
✍ Scribed by Fay W. Ng; Hong Lin; Qiang Tan; Samuel J. Danishefsky
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 27 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Abstract
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