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ChemInform Abstract: The Synthesis and Some Ring-Opening Reactions of N,O-bis( Diphenylphosphinyl) Hydroxymethylaziridine.

โœ Scribed by A. A. CANTRILL; J. B. SWEENEY

Book ID
112030551
Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
27
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Preparation and Rin
ChemInform Abstract: Preparation and Ring-Opening Reactions of N-Diphenylphosphinyl Vinyl Aziridines.
โœ A. A. CANTRILL; A. N. JARVIS; H. M. I. OSBORN; A. OUADI; J. B. SWEENEY ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 33 KB ๐Ÿ‘ 2 views

Preparation and Ring-Opening Reactions of N-Diphenylphosphinyl Vinyl Aziridines. -LDA-Lithiation of allyl bromide (I) followed by ZnCl2 generates ฮฑ -bromo allyllithium which reacts with phosphinyl aldimines to form mainly trans-or cis-aziridines depending on the substituent R. The arylated trans-der