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ChemInform Abstract: Preparation and Ring-Opening Reactions of N-Diphenylphosphinyl Aziridines.

โœ Scribed by A. A. CANTRILL; H. M. I. OSBORN; J. SWEENEY


Publisher
John Wiley and Sons
Year
2010
Weight
38 KB
Volume
29
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Preparation and Rin
โœ A. A. CANTRILL; A. N. JARVIS; H. M. I. OSBORN; A. OUADI; J. B. SWEENEY ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 33 KB ๐Ÿ‘ 2 views

Preparation and Ring-Opening Reactions of N-Diphenylphosphinyl Vinyl Aziridines. -LDA-Lithiation of allyl bromide (I) followed by ZnCl2 generates ฮฑ -bromo allyllithium which reacts with phosphinyl aldimines to form mainly trans-or cis-aziridines depending on the substituent R. The arylated trans-der