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Preparation and Ring-Opening Reactions of N,O-Bis(diphenylphosphinyl) Hydroxymethylaziridine (“Di-Dpp”).

✍ Scribed by J. B. Sweeney; Alex A. Cantrill

Publisher
John Wiley and Sons
Year
2003
Weight
197 KB
Volume
34
Category
Article
ISSN
0931-7597

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Preparation and Ring-Opening Reactions of N-Diphenylphosphinyl Vinyl Aziridines. -LDA-Lithiation of allyl bromide (I) followed by ZnCl2 generates α -bromo allyllithium which reacts with phosphinyl aldimines to form mainly trans-or cis-aziridines depending on the substituent R. The arylated trans-der