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ChemInform Abstract: The Importance of Polar, Resonance, Steric and Solvent Effects in the Addition of Sulfonyl Radicals to Alkenes.

✍ Scribed by C. M. M. DA SILVA CORREA; M. D. C. M. FLEMING; M. A. B. C. S. OLIVEIRA; E. M. J. GARRIDO

Book ID
112021100
Publisher
John Wiley and Sons
Year
2010
Weight
23 KB
Volume
26
Category
Article
ISSN
0931-7597

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Polar Effects in the Addition of Alkyl R
Polar Effects in the Addition of Alkyl Radicals to Olefins
✍ Priv.-Doz. Dr. Bernd Giese; Dipl.-Chem. JΓΌrgen Meister πŸ“‚ Article πŸ“… 1977 πŸ› John Wiley and Sons 🌐 English βš– 198 KB πŸ‘ 2 views

**The presence of a negative partial charge on the benzylic carbon atom in the transition state** __(1)__ can be deduced from the experimentally determinable Hammett Ο± values. Alkyl radicals R^Λ™^ are accordingly seen to develop nucleophilic properties during addition to olefins. equation image