ChemInform Abstract: The First Total Synthesis of the Naturally Occurring Germination Stimulant Sorgolactone (XII).
β Scribed by Y. SUGIMOTO; S. C. M. WIGCHERT; J. W. J. F. THURING; B. ZWANENBURG
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 30 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0931-7597
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Synthesis of (3aR,8S,8bS,2'R)-(+)-Sorgolactone and Its Stereoisomers, the Germination Stimulant from Sorghum bicolor. -The total synthesis of the title compound (IX) or its stereoisomers [cf. (X)] is based on the radical cyclization of the methyl (S)-citronellate derived phenylselenylated ester (II
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