ChemInform Abstract: The Dicobaltoctacarbonyl Catalyzed Polymerization of Allylic Ethers.
โ Scribed by J. V. CRIVELLO; S. K. RAJARAMAN
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 31 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0931-7597
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In the presence of silanes bearing Si{H groups, dicobalt octacarbonyl [Co 2 (CO) 8 ] efficiently catalyzes the cationic polymerization of a wide variety of enol ether and other related monomers including vinyl ethers, 1-propenyl ethers, 1-butenyl ethers, 2,3-dihydrofuran, 3,4-dihydro-2H-pyran, keten
Alkyl allyl ethers undergo facile thermally induced isomerization to alkyl 1-propenyl ethers in the presence of Group VIII transition metal carbonyl compounds as catalysts. The addition of a silane containing a Si-H bond to these systems results in a catalyst system that is capable of not only isome