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ChemInform Abstract: Pd-Catalyzed Synthesis of Allylic Silanes from Allylic Ethers.

✍ Scribed by Ralph Moser; Takashi Nishikata; Bruce H. Lipshutz


Publisher
John Wiley and Sons
Year
2010
Weight
48 KB
Volume
41
Category
Article
ISSN
0931-7597

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The first copper-catalyzed allylic substitution reactions of allylic acetates and carbamates employing a bis(triorganosilyl)zinc reagent are reported. This novel procedure avoids the use of stoichiometric amounts of copper salts which are usually mandatory with this chemistry. Application of this me