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ChemInform Abstract: The Detection of O=SiCl2 as an Intermediate During the Combustion Process of SiCl4 with O2.

✍ Scribed by Markus Junker; Andreas Wilkening; Michael Binnewies; Hansgeorg Schnoeckel


Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
30
Category
Article
ISSN
0931-7597

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The Detection of O=SiCl2 as an Intermedi
✍ Markus Junker; Andreas Wilkening; Michael Binnewies; Hansgeorg SchnΓΆckel πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 270 KB πŸ‘ 2 views

During the technical important combustion of SiCl 4 with calculations the thermodynamic data have been calculated first. On this basis it was possible to find the optimal oxygen [SiCl 4 (g) + O 2 (g) = SiO 2 (s) + 2β€’Cl 2 (g)] many intermediates have been detected in the past. However, the conditions

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✍ Hans-JΓΆrg Himmel; Nils SchiefenhΓΆvel; Michael Binnewies πŸ“‚ Article πŸ“… 2003 πŸ› John Wiley and Sons 🌐 English βš– 150 KB

## Abstract We studied the reaction of SiCl~4~ with NH~3~ by mass spectrometry and IR spectroscopy. By means of mass spectrometry, SiCl~3~NH~2~ was for the first time identified as an intermediate generated in significant amounts in the course of the reaction. In additional experiments, SiCl~3~NH~2