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ChemInform Abstract: The Beckmann Rearrangement of Cyclohex-2-enone Oximes. Synthesis of 4, 5-Diphenyl-2,3,4,5-tetrahydro-1H-azepin-2-one.

✍ Scribed by J. W. LYGA

Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
28
Category
Article
ISSN
0931-7597

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✦ Synopsis

The Beckmann Rearrangement of Cyclohex-2-enone Oximes. Synthesis of 4, 5-Diphenyl-2,3,4,5-tetrahydro-1H-azepin-2-one.

-The title compound (VI), which is an intermediate for the preparation of certain pesticides, can be prepared from both isomeric oximes (IV) and (V). In contrast, only the syn oxime tosylate (VIII) undergoes this type of reaction. -(LYGA,

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✍ S. BOZZINI; P. NITTI; G. PITACCO; A. PIZZIOLI; C. RUSSO πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 29 KB πŸ‘ 1 views

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