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ChemInform Abstract: Asymmetric Synthesis of 1-Aryl 2,3,4,5-Tetrahydro-2-benz[c]azepines.

โœ Scribed by Rocio Gamez-Montano; Maria Isabel Chavez; Georges Roussi; Raymundo Cruz-Almanza

Publisher
John Wiley and Sons
Year
2001
Weight
29 KB
Volume
32
Category
Article
ISSN
0931-7597

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โœ J. W. LYGA ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 30 KB ๐Ÿ‘ 1 views

The Beckmann Rearrangement of Cyclohex-2-enone Oximes. Synthesis of 4, 5-Diphenyl-2,3,4,5-tetrahydro-1H-azepin-2-one. -The title compound (VI), which is an intermediate for the preparation of certain pesticides, can be prepared from both isomeric oximes (IV) and (V). In contrast, only the syn oxime