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ChemInform Abstract: The [1,3] O-to-C Rearrangement: Opportunities for Stereoselective Synthesis

✍ Scribed by Christopher G. Nasveschuk; Tomislav Rovis


Publisher
John Wiley and Sons
Year
2008
Weight
15 KB
Volume
39
Category
Article
ISSN
0931-7597

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✍ Julien C. R. Brioche; Thomas A. Barker; David J. Whatrup; Michael D. Barker; Jos 📂 Article 📅 2011 🏛 John Wiley and Sons ⚖ 33 KB

## Abstract Rearrangement of the pyran‐based aryl enol ethers proceeds with nearly complete diastereoselectivity affording the (E)‐trans products, regardless whether (E)‐ or (Z)‐substrates are being used.