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ChemInform Abstract: Palladium-Catalyzed [1,3]-O-to-C Rearrangement of Pyrans Toward Functionalized Cyclohexanones.

✍ Scribed by Julien C. R. Brioche; Thomas A. Barker; David J. Whatrup; Michael D. Barker; Joseph P. A. Harrity

Publisher: John Wiley and Sons
Year: 2011
Weight: 33 KB
Volume: 42
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201109059

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✦ Synopsis

Abstract

Rearrangement of the pyran‐based aryl enol ethers proceeds with nearly complete diastereoselectivity affording the (E)‐trans products, regardless whether (E)‐ or (Z)‐substrates are being used.

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