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ChemInform Abstract: [Ta6Cl12(PrCN)6] [(Ta6Cl12)Cl6]×2PrCN, a Compound with Homonuclear Mixed-Charge Cluster Units [Ta6Cl12]2+ and [Ta6Cl12]4+.

✍ Scribed by Nevenka Brnicevic; Sinisa Sirac; Ivan Basic; Zhihong Zhang; Robert E. McCarley; Ilia A. Guzei


Publisher
John Wiley and Sons
Year
2010
Weight
36 KB
Volume
30
Category
Article
ISSN
0931-7597

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Compounds consisting of both cluster cations and cluster anions of the composition [(M 6 X 12 )(EtOH) 6 ][(Mo 6 Cl 8 )Cl 4 X 2 ] ´n EtOH ´m Et 2 O (M = Nb, Ta; X = Cl, Br) have been prepared by the reaction of (M 6 X 12 )X 2 ´6 EtOH with (Mo 6 Cl 8 )Cl 4 . IR data are given for three compounds. The