ChemInform Abstract: Synthesis, Properties and Crystal Structure of α-Ca3(BN2)2 and Ca9+x(BN2,CBN)6 — Two Compounds with BN3-2 and CBN4- Anions.
✍ Scribed by M. WOERLE; H. MEYER ZU ALTENSCHILDESCHE; R. NESPER
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 37 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0931-7597
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📜 SIMILAR VOLUMES
Nitridoborates. Part 1. LiMg(BN2) (I) and Ba4(BN2)2O (II) -Compounds with the Anion (N-B-N)3-: Syntheses, Crystal Structures, and Vibrational Spectra. -The title compounds are prepared by solid state reaction of stoichiometric mixtures of Li3N, Mg3N2, and BN for (I) and BaO, Ba3N2, and BN for (II)
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## Abstract The title compound is prepared by solid state reaction of a stoichiometric mixture of Mg~3~N~2~, BN, and MgBr~2~ (sealed Nb ampule, 1473 K, 24 h, slow cooling).