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ChemInform Abstract: Synthesis, Crystal Structure and Vibrational Spectra of Mg2[BN2]Br: A New Magnesium Nitridoborate Halide with Discrete [N—B—N]3- Groups.

✍ Scribed by Ilkin Kokal; Mehmet Somer; Lev Akselrud; Peter Hoehn; Wilder Carrillo-Cabrera

Publisher
John Wiley and Sons
Year
2011
Weight
19 KB
Volume
42
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

The title compound is prepared by solid state reaction of a stoichiometric mixture of Mg~3~N~2~, BN, and MgBr~2~ (sealed Nb ampule, 1473 K, 24 h, slow cooling).

📜 SIMILAR VOLUMES

ChemInform Abstract: Ternary Nitridobora
ChemInform Abstract: Ternary Nitridoborates. Part 1. LiMg(BN2) (I) and Ba4(BN2)2O (II) - Compounds with the Anion (N-B-N)3-: Syntheses, Crystal Structures, and Vibrational Spectra.
✍ M. SOMER; U. HERTERICH; J. CURDA; W. CARRILLO-CABRERA; K. PETERS; H. G. VON SCHN 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 29 KB 👁 2 views

Nitridoborates. Part 1. LiMg(BN2) (I) and Ba4(BN2)2O (II) -Compounds with the Anion (N-B-N)3-: Syntheses, Crystal Structures, and Vibrational Spectra. -The title compounds are prepared by solid state reaction of stoichiometric mixtures of Li3N, Mg3N2, and BN for (I) and BaO, Ba3N2, and BN for (II)