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ChemInform Abstract: Synthesis of Thiazoles from the Reaction of Phenyliodonium Ylides of Cyclic β-Dicarbonyl Compounds with Thioureas.

✍ Scribed by H. KAMPROUDI; S. SPYROUDIS; P. TARANTILI

Book ID
112041396
Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
27
Category
Article
ISSN
0931-7597

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Reaction of phenyliodonium ylides of β-d
Reaction of phenyliodonium ylides of β-dicarbonyl compounds with allylic sulfides and selenides
✍ Rui-Yang Yang; Li-Xin Dai; Ru-Jian Ma 📂 Article 📅 1992 🏛 John Wiley and Sons 🌐 English ⚖ 332 KB

## Abstract An efficient and mild reaction for introducing an allylic moiety and an alkylthio‐ or alkylseleno‐group onto the α‐carbon of β‐dicarbonyl compounds in one step by tandem transylidation and [2,3]‐sigmatropic rearrangement is described.