ChemInform Abstract: Synthesis of Regioselectively Deuterated Cyclopropanes.
β Scribed by J.-M. DUFFAULT; P. HANOTEAU; A. PARRILLA; J. EINHORN
- Book ID
- 112040689
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 26 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0931-7597
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Regioselective Cyclopropanation Reactions Using Iodonium Ylides: Synthesis of Prostaglandin Precursors. -Base-promoted reaction of Ξ²-keto esters (I) and (V) with iodobenzene diacetate provides iodonium ylides. Their Cu(I)-catalyzed decomposition results in intramolecular cyclopropanation with a cle
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