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ChemInform Abstract: Synthesis of (.+-.)-Pseudoheliotridane by Allylboration of 1-Pyrroline.

✍ Scribed by M. E. GURSKII; T. V. POTAPOVA; YU. N. BUBNOV

Publisher: John Wiley and Sons
Year: 2010
Weight: 30 KB
Volume: 29
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199842215

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Enantioselective Synthesis of Optically Active Homoallylamines by Allylboration of N-Diisobutylaluminum Imines. -A convenient synthesis of optically active homoallylamines (III) and (VI) is presented. It involves the enantioselective allylboration of title aluminum imines (I) and (V), resp., with c