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ChemInform Abstract: Enantioselective Synthesis of Optically Active Homoallylamines by Allylboration of N-Diisobutylaluminum Imines.

โœ Scribed by Katsuhiro Watanabe; Shizue Kuroda; Ayako Yokoi; Koichi Ito; Shinichi Itsuno

Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
30
Category
Article
ISSN
0931-7597

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โœฆ Synopsis

Enantioselective Synthesis of Optically Active Homoallylamines by Allylboration of N-Diisobutylaluminum Imines.

-A convenient synthesis of optically active homoallylamines (III) and (VI) is presented. It involves the enantioselective allylboration of title aluminum imines (I) and (V), resp., with chirally modified allylboron reagents like (II) or (IV). -

๐Ÿ“œ SIMILAR VOLUMES

ChemInform Abstract: Enantioselective Sy
ChemInform Abstract: Enantioselective Synthesis of Optically Active Homoallylamines by Nucleophilic Addition of Chirally Modified Allylboranes to N-Silylimines.
โœ Shinichi Itsuno; Katsuhiro Watanabe; Takeshi Matsumoto; Shizue Kuroda; Ayako Yok ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 36 KB ๐Ÿ‘ 1 views

Enantioselective Synthesis of Optically Active Homoallylamines by Nucleophilic Addition of Chirally Modified Allylboranes to N-Silylimines. -A variety of chirally modified allylboron reagents, readily generated from the corresponding chiral bidentate ligands and triallylborane in the presence of Et