Indoles undergo reductive α-allylation upon treatment with allylic boranes (triallyl-and triprenylborane) to give, after deboronation, the corresponding 2-allylated indolines in 70-85% yield. 1,2-Addition of the allylboron fragment to heterocycles occurs with full rearrangement of the allylic moiety
✦ LIBER ✦
ChemInform Abstract: Reductive 1,2-Allylboration of Indoles by Triallyl- and Triprenylborane — Synthesis of 2-Allylated Indolines.
✍ Scribed by Yury N. Bubnov; Ilya V. Zhun'; Elena V. Klimkina; Anatoly V. Ignatenko; Zoya A. Starikova
- Publisher
- John Wiley and Sons
- Year
- 2001
- Weight
- 29 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0931-7597
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