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ChemInform Abstract: Reductive 1,2-Allylboration of Indoles by Triallyl- and Triprenylborane — Synthesis of 2-Allylated Indolines.

✍ Scribed by Yury N. Bubnov; Ilya V. Zhun'; Elena V. Klimkina; Anatoly V. Ignatenko; Zoya A. Starikova


Publisher
John Wiley and Sons
Year
2001
Weight
29 KB
Volume
32
Category
Article
ISSN
0931-7597

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Reductive 1,2-Allylboration of Indoles b
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Indoles undergo reductive α-allylation upon treatment with allylic boranes (triallyl-and triprenylborane) to give, after deboronation, the corresponding 2-allylated indolines in 70-85% yield. 1,2-Addition of the allylboron fragment to heterocycles occurs with full rearrangement of the allylic moiety

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