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ChemInform Abstract: Synthesis of Heterocycles Using Zirconium-Catalyzed Asymmetric Diene Cyclization.

✍ Scribed by Y. YAMAURA; M. HYAKUTAKE; M. MORI

Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
28
Category
Article
ISSN
0931-7597

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Enantioselective Synthesis of Cyclopentane Derivatives Using Zirconium-Catalyzed Asymmetric Cyclization. -The cyclization of dienes such as (I), (IV), and (VI) in the presence of Bu-MgCl and a chiral Zr-catalyst is studied. Optically active highly substituted cyclopentanes are obtained in good to h