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ChemInform Abstract: Total Synthesis of (+)-Xestoquinone Using an Asymmetric Palladium- Catalyzed Polyene Cyclization.

โœ Scribed by S. P. MADDAFORD; N. G. ANDERSEN; W. A. CRISTOFOLI; B. A. KEAY


Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
28
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Remote Substituent
โœ Stephen Y. W. Lau; Brian A. Keay ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 31 KB ๐Ÿ‘ 2 views

Remote Substituent Effects on the Enantiomeric Excess of Intramolecular Asymmetric Palladium-Catalyzed Polyene Cyclizations. -Remote substituents show a strong influence on the enantioselectivity of the title reactions. Excellent enantioselectivity is obtained by cyclization of the O-methyl triflate