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ChemInform Abstract: Enantioselective Synthesis of Cyclopentane Derivatives Using Zirconium-Catalyzed Asymmetric Cyclization.

✍ Scribed by Yousuke Yamaura; Miwako Mori

Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis

Enantioselective Synthesis of Cyclopentane Derivatives Using Zirconium-Catalyzed Asymmetric Cyclization.

-The cyclization of dienes such as (I), (IV), and (VI) in the presence of Bu-MgCl and a chiral Zr-catalyst is studied. Optically active highly substituted cyclopentanes are obtained in good to high enantioselectivities. -(YAMAURA, YOUSUKE;

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