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ChemInform Abstract: Synthesis of 3-Perfluoroalkylprop-1-enes RF-CH2-CH=CH2.

✍ Scribed by S. Rubio; H. Blancou; A. Commeyras

Publisher: John Wiley and Sons
Year: 2010
Weight: 31 KB
Volume: 31
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200009077

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Excess molar volumes of {x1CH3CH2COOCH2CH3+x2CH3(CH2)4CH3+ (1 −x1−x2)CH3(CH2)2OH or CH3(CH2)3OH} at the temperature 298.15 K

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Excess molar volumes at the temperature 298.15 K were measured for , and {xCH3(CH2)4 CH3 +(1x)CH3(CH2)3OH}. Excess molar volumes were determined using an Anton Paar DMA 60/602 densimeter. The experimental values obtained in this work were compared with results obtained using methods which estimate

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## Excess molar volumes at CH2 )n-2CH3}, (n= 10 or n = 12), and {xCH3(CH2)3CH2Cl + (1x)CH3(CH2)n-2CH3}, (n= 10 or n = 12), were determined using a densimeter Anton Paar DMA 60/602. All the experimental values were compared with the results obtained by empirical expressions for estimating ternar

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Excess molar volumes at the temperature 298.15 K of the ternary mixtures: , and of the binary mixtures: , and {xCH3(CH2)5OH + (1-x)Cl(CH2)5CH3} were determined using a densimeter. All the experimental values were compared with the results obtained by empirical expressions for estimating ternary pr

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Excess molar enthalpies at the temperature 298.15 K were measured for CH2)nCH3} (n = 9, 12), and {x2CH3(CH2)4CH3 + (1-x2)CH3(CH2)n-2CH3} (n=9, 12), using a Calvet microcalorimeter. The experimental results were compared with those calculated by using the Nitta-and-Chao model.