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ChemInform Abstract: Synthesis of (2S,3R,4S)-3,4-Methanoproline and Analogues by Cyclopropylidene Insertion.

✍ Scribed by V. V. TVEREZOVSKY; M. S. BAIRD; I. G. BOLESOV


Publisher
John Wiley and Sons
Year
2010
Weight
40 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis


Synthesis of (2S,3R,4S)-3,4-Methanoproline and Analogues by Cyclopropylidene Insertion.

-The key steps in the synthesis of the title compounds (IX), (XIII), and (XVI) are stereoselective cyclization of the bromides (V), (X), and (XIV) and oxidation of the bicyclic derivatives (VIII), (XII), and (XV). -(


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