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ChemInform Abstract: Stereoselective Synthesis of (2R, 3R)- and (2S, 3S)-2-(4-Hydroxyphenyl)-3-hydroxymethyl-1,4-benzodioxan-6-carbaldehyde.

โœ Scribed by Wenxin Gu; Xiaochuan Chen; Xiaobi Jing; Xinfu Pan


Publisher
John Wiley and Sons
Year
2001
Weight
30 KB
Volume
32
Category
Article
ISSN
0931-7597

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A Convenient Stereoselective Synthesis of (1R,2S,3R,4S)-3-(Neopentyloxy)isoborneol. -The first regio-and stereoselective synthesis of the title compound (VI), a valuable chiral auxiliary, is developed starting from the camphorquinone (I) in six steps and 48% overall yield. -