ChemInform Abstract: Synthesis of (2-(Dimethylphosphino)ethyl)bis(trifluoromethyl)phosphine, (CH3)2PCH2CH2P(CF3)2.
β Scribed by L. D. FIELD; M. P. WILKINSON
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 29 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Abstract
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π SIMILAR VOLUMES
The reactions of Zn(CF 3 )Br Β΄2 CH 3 CN, Cd(CF 3 ) 2 Β΄2 CH 3 CN or Bi(CF 3 ) 3 /AlCl 3 with tertiary amines lead to the formation of quaternary ammonium salts of the general formula [R 3 NCF 2 H]X. The reaction of 4-N,N-dimethylaminopyridine with Zn(CF 3 )Br Β΄2 CH 3 CN yields (Ndifluoromethyl)-4-N,N
The complexes [RhCl (3Γn) (MeCN) n (CF 3 triphos)](CF 3 SO 3 ) n (n 1, 2; CF 3 triphos MeC[CH 2 P(m-CF 3 C 6 H 4 ) 2 ] 3 ) and [M(MeCN) 3 (CF 3 triphos)](CF 3 SO 3 ) n (M Ru, n 2; M Ir, n 3) are catalyst precursors for some typical acetalization and transacetalization reactions. The activity of thes