ChemInform Abstract: Acetalization and Transacetalization Reactions Catalyzed by Ruthenium, Rhodium, and Iridium Complexes with {2-{{Bis[3-(trifluoromethyl)phenyl] phosphino}methyl}-2-methylpropane-1,3-diyl}bis[bis [3-(trifluoromethyl)phenyl]phosphine] (MeC[CH2P (m-CF3C6H4)2]3).

Acetalization and Transacetalization Rea

Acetalization and Transacetalization Reactions Catalyzed by Ruthenium, Rhodium, and Iridium Complexes with {2-{{Bis[3-(trifluoromethyl)phenyl]phosphino}methyl}-2-methylpropane- 1,3-diyl}bis[bis[3-(trifluoromethyl)phenyl]phosphine] (MeC[CH2P(m-CF3C6H4)2]3)

✍ Mustafa Sülü; Luigi M. Venanzi 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 German ⚖ 123 KB 👁 1 views

The complexes [RhCl (3Àn) (MeCN) n (CF 3 triphos)](CF 3 SO 3 ) n (n 1, 2; CF 3 triphos MeC[CH 2 P(m-CF 3 C 6 H 4 ) 2 ] 3 ) and [M(MeCN) 3 (CF 3 triphos)](CF 3 SO 3 ) n (M Ru, n 2; M Ir, n 3) are catalyst precursors for some typical acetalization and transacetalization reactions. The activity of thes